Axial Addition in Diastereoisomeric [Ni(Me8[14]ane)](ClO4)2 Complexes and Their Antifungal Activities

A series of diastereoisomeric square planar nickel(II) diperchlorate complexes, [Ni(L)](ClO4)2{L= isomeric Me8[14]ane (LAα, LBα or LCα)}undergo axial ligand addition reactions with NO3-, Cl-, Br-, SCN- ClO4- to yield six coordinate octahedral derivatives [NiL(X)x(Y)y].z(H2O)(X=NO3,Cl, Br SCN; Y= ClO4; x = 1 2; y 0 and z 0, 2). The products have been characterized on the basis analytical, spectroscopic, magnetic conductance data. All are unstable in open air except one derivative revert back original complexes. Antifungal activities ligands their complexes investigated against some phytopathogenic fungi.
 Chittagong Univ. J. Sci. 40(1) : 122-147, 2019